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ANILINE FOR SYNTHESIS LR GRADE
|Synonyms||Aminobenzene, Phenylamine, Benzenamine|
|HS Code||2921 41 00|
|Molar mass||93.13 g/mol|
|EC index number||612-008-00-7|
|Chemical and physical data|
|Ignition temperature||540 °C|
|Solubility||36 g/l (20 °C)|
|Saturation concentration (air)||2 g/m3 (20 °C) Air|
|Melting point||-6.2 °C|
|Molar mass||93.13 g/mol|
|Density||1.02 g/cm3 (20 °C)|
|pH value||8.8 (36 g/l, H2O, 20 °C)|
|Boiling point||184 °C (1013 hPa)|
|Vapor pressure||0.5 hPa (20 °C)|
|Explosion limit||1.2 - 11 %(V)|
|Flash point||76 °C|
|Refractive index||1.5863 (20 °C, 589 nm)|
|Water absorption||540 g/kg (30 °C)|
|Safety information according to GHS|
|Hazard Statement(s)||H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H341: Suspected of causing genetic defects.
H351: Suspected of causing cancer.
H372: Causes damage to organs (/$/*_ORGAN_REPEAT/$/) through prolonged or repeated exposure.
H400: Very toxic to aquatic life.
|Precautionary Statement(s)||P273: Avoid release to the environment.
P280: Wear protective gloves.
P280: Wear eye protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P309 + P310: IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
|Storage class||6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials|
|WGK||WGK 2 water endangering|
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
|R Phrase||R 23/24/25-40-41-43-48/23/24/25-68-50
Toxic by inhalation, in contact with skin and if swallowed.Limited evidence of a carcinogenic effect.Risk of serious damage to eyes.May cause sensitisation by skin contact.Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.Possible risk of irreversible effects.Very toxic to aquatic organisms.
|S Phrase||S 26-27-36/37/39-45-46-61-63
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).If swallowed, seek medical advice immediately and show this container or label.Avoid release to the environment. Refer to special instructions/ Safety data sheets.In case of accident by inhalation: remove casualty to fresh air and keep at rest.
|Categories of danger||toxic, carcinogenic, irritant, sensitizing, mutagenic, dangerous for the environment|
|Declaration (railroad and road) ADR, RID||UN 1547 Anilin, 6.1, II|
|Declaration (transport by sea) IMDG-Code||UN 1547 ANILINE, 6.1, II, Marine Pollutant: P|
|Declaration (transport by air) IATA-DGR||UN 1547 ANILINE, 6.1, II|
|LD 50 oral||LD50 rat 871 mg/kg|
|LD 50 dermal||LD50 rabbit 840 mg/kg|